33 S NMR: Recent Advances and Applications.

The purpose of this review is to present advances and applications of 33 S NMR, which is an underutilized NMR spectroscopy. Experimental NMR aspects in solution, chemical shift tendencies, and quadrupolar relaxation parameters will be briefly summarized. Emphasis will be given to advances and applications in the emerging fields of solid-state and DFT computations of 33 S NMR parameters. The majority of the examples were taken from the last twenty years and were selected on the basis of their importance to provide structural, electronic, and dynamic information that is difficult to obtain by other techniques.