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Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer.

Takashi NakamuraShinnosuke TsukudaTatsuya Nabeshima
Published in: Journal of the American Chemical Society (2019)
Belt-shaped macrocycles possessing saloph units as their walls have been generated by the double-circular connection of a bis-armed bifunctional monomer bearing both o-phenylenediamine and salicylaldehyde functionalities. The saloph-belt macrocycles showed unique properties, such as the selective inclusion of fullerenes ( Ka(C70)/ Ka(C60) > 100), utilizing their rigid scaffolds.
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