In the search for next-generation green energy storage solutions, Cu-S electrochemistry has recently gained attraction from the battery community owing to its affordability and exceptionally high specific capacity of 3350 mAh g s -1 . However, the inferior conductivity and substantial volume expansion of the S cathode hinder its cycling stability, while the low output voltage limits its energy density. Herein, a hollow carbon sphere (HCS) is synthesized as a 3D conductive host to achieve a stable S@HCS cathode, which enables an outstanding cycling performance of 2500 cycles (over 9 months). To address the latter, a Zn//S@HCS alkaline-acid decoupled cell is configured to increase the output voltage from 0.18 to 1.6 V. Moreover, an electrode and electrolyte co-energy storage mechanism is proposed to offset the reduction in energy density resulting from the extra electrolyte required in Zn//S decoupled cells. When combined, the Zn//S@HCS alkaline-acid decoupled cell delivers a record energy density of 334 Wh kg -1 based on the mass of the S cathode and CuSO 4 electrolyte. This work tackles the key challenges of Cu-S electrochemistry and brings new insights into the rational design of decoupled batteries.