Excellent Catalytic Performance of ISOBAM Stabilized Co/Fe Colloidal Catalysts toward KBH 4 Hydrolysis.

Recently, developing a cost-effective and high-performance catalyst is regarded as an urgent priority for hydrogen generation technology. In this work, ISOBAM-104 stabilized Co/Fe colloidal catalysts were prepared via a co-reduction method and used for the hydrogen generation from KBH 4 hydrolysis. The obtained ISOBAM-104 stabilized Co 10 Fe 90 colloidal catalysts exhibit an outstanding catalytic activity of 37,900 mL-H 2 min -1 g-Co -1 , which is far higher than that of Fe or Co monometallic nanoparticles (MNPs). The apparent activation energy ( E a ) of the as-prepared Co 10 Fe 90 colloidal catalysts is only 14.6 ± 0.7 kJ mol -1 , which is much lower than that of previous reported noble metal-based catalysts. The X-ray photoelectron spectroscopy results and density functional theory calculations demonstrate that the electron transfer between Fe and Co atoms is beneficial for the catalytic hydrolysis of KBH 4 .