A 1D Coordination Polymer of UF5 with HCN as a Ligand.
Benjamin ScheibeStefan S RudelMagnus R BuchnerAntti J KarttunenFlorian KrausPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2016)
β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition 1∞ [UF5 (HCN)2 ], 1∞ [UF4/1 F2/2 - (HCN)2/1 ], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.
Keyphrases
- density functional theory
- molecular dynamics
- drinking water
- molecular dynamics simulations
- drug delivery
- high resolution
- computed tomography
- cancer therapy
- energy transfer
- ionic liquid
- magnetic resonance
- molecularly imprinted
- monte carlo
- fluorescent probe
- drug release
- raman spectroscopy
- solid phase extraction
- visible light