Enhanced Electromagnetic Wave Absorption Properties of Ultrathin MnO 2 Nanosheet-Decorated Spherical Flower-Shaped Carbonyl Iron Powder.

In this work, spherical flower-shaped composite carbonyl iron powder@MnO 2 (CIP@MnO 2 ) with CIP as the core and ultrathin MnO 2 nanosheets as the shell was successfully prepared by a simple redox reaction to improve oxidation resistance and electromagnetic wave absorption properties. The microwave-absorbing properties of CIP@MnO 2 composites with different filling ratios (mass fractions of 20%, 40%, and 60% after mixing with paraffin) were tested and analyzed. The experimental results show that compared with pure CIP, the CIP@MnO 2 composites have smaller minimum reflection loss and a wider effective absorption bandwidth than CIP (RL < -20 dB). The sample filled with 40 wt% has the best comprehensive performance, the minimum reflection loss is -63.87 dB at 6.32 GHz, and the effective absorption bandwidth (RL < -20 dB) reaches 7.28 GHz in the range of 5.92 GHz-9.28 GHz and 11.2 GHz-15.12 GHz, which covers most C and X bands. Such excellent microwave absorption performance of the spherical flower-like CIP@MnO 2 composites is attributed to the combined effect of multiple beneficial components and the electromagnetic attenuation ability generated by the special spherical flower-like structure. Furthermore, this spherical flower-like core-shell shape aids in the creation of discontinuous networks, which improve microwave incidence dispersion, polarize more interfacial charges, and allow electromagnetic wave absorption. In theory, this research could lead to a simple and efficient process for producing spherical flower-shaped CIP@MnO 2 composites with high absorption, a wide band, and oxidation resistance for a wide range of applications.