Performance and Stability of Polymer : Nonfullerene Solar Cells with 100 °C-Annealed Electron-Collecting Combination Layers.

Inverted-type organic solar cells, fabricated with low-temperature-processed combination layers of hybrid electron-collecting buffer layers (ECBLs) consisting of zinc oxide (ZnO) and poly(2-ethyl-2-oxazoline) (PEOz) and additional PEOz interlayers, showed improved performance and stability. The ZnO : PEOz precursor films with various PEOz compositions (0-12 wt %) were prepared and thermally treated at 100 °C, leading to the ECBLs on which the PEOz interlayers were subsequently deposited before coating of polymer : nonfullerene bulk heterojunction layers. Results showed that the power conversion efficiency of solar cells reached approximately 9.38 and 10.11 % (average) in case of the ZnO/PEOz and ZnO : PEOz(6 wt % PEOz)/PEOz combination layers, respectively, despite the low-temperature thermal annealing process. A continuous irradiation test for 12 h under one sun condition (air mass 1.5G, 100 mW cm-2 ) disclosed that the devices with the ZnO : PEOz(6 wt % PEOz)/PEOz combination layers were more stable than those with the ZnO/PEOz layers.