Integrating TiO₂/SiO₂ into Electrospun Carbon Nanofibers towards Superior Lithium Storage Performance.

In order to overcome the poor electrical conductivity of titania (TiO₂) and silica (SiO₂) anode materials for lithium ion batteries (LIBs), we herein report a facile preparation of integrated titania⁻silica⁻carbon (TSC) nanofibers via electrospinning and subsequent heat-treatment. Both titania and silica are successfully embedded into the conductive N-doped carbon nanofibers, and they synergistically reinforce the overall strength of the TSC nanofibers after annealing (Note that titania⁻carbon or silica⁻carbon nanofibers cannot be obtained under the same condition). When applied as an anode for LIBs, the TSC nanofiber electrode shows superior cycle stability (502 mAh/g at 100 mA/g after 300 cycles) and high rate capability (572, 518, 421, 334, and 232 mAh/g each after 10 cycles at 100, 200, 500, 1000 and 2000 mA/g, respectively). Our results demonstrate that integration of titania/silica into N-doped carbon nanofibers greatly enhances the electrode conductivity and the overall structural stability of the TSC nanofibers upon repeated lithiation/delithiation cycling.