A new view on the origin of zero-bias anomalies of Co atoms atop noble metal surfaces.
Juba BouazizFilipe Souza Mendes GuimarãesSamir LounisPublished in: Nature communications (2020)
Many-body phenomena are paramount in physics. In condensed matter, their hallmark is considerable on a wide range of material characteristics spanning electronic, magnetic, thermodynamic and transport properties. They potentially imprint non-trivial signatures in spectroscopic measurements, such as those assigned to Kondo, excitonic and polaronic features, whose emergence depends on the involved degrees of freedom. Here, we address systematically zero-bias anomalies detected by scanning tunneling spectroscopy on Co atoms deposited on Cu, Ag and Au(111) substrates, which remarkably are almost identical to those obtained from first-principles. These features originate from gaped spin-excitations induced by a finite magnetic anisotropy energy, in contrast to the usual widespread interpretation relating them to Kondo resonances. Resting on relativistic time-dependent density functional and many-body perturbation theories, we furthermore unveil a new many-body feature, the spinaron, resulting from the interaction of electrons and spin-excitations localizing electronic states in a well defined energy.
Keyphrases
- single molecule
- high resolution
- molecularly imprinted
- room temperature
- magnetic resonance
- density functional theory
- machine learning
- molecular docking
- heart rate
- mass spectrometry
- deep learning
- gene expression
- escherichia coli
- sensitive detection
- biofilm formation
- staphylococcus aureus
- dna methylation
- reduced graphene oxide
- pseudomonas aeruginosa
- molecular dynamics
- metal organic framework