Tungsten disulfide (WS 2 ) is considered as a promising anode material for high-performance lithium-ion batteries (LIBs) result from its inherent characteristics such as high theoretical capacity, large interlayer spacing and weak interlayer Van der Waals force. Nevertheless, WS 2 has the drawbacks of easy agglomeration, severe volume expansion and high Li + migration barrier, which lead to rapid capacity degradation and imperfect rate ability. In this work, a novel two-dimensional (2D) hierarchical composite (Ti 3 C 2 /WS 2 ) consisting of WS 2 nanosheets vertically grown on titanium carbide (Ti 3 C 2 ) nanosheets is prepared. Thanks to this distinctive hierarchical structure and synergy between WS 2 and Ti 3 C 2 , the Ti 3 C 2 /WS 2 composite demonstrates exceptional electrochemical performance in LIBs. In addition, we investigate the effect of the mass proportion of WS 2 in Ti 3 C 2 /WS 2 composite on the electrochemical performance, and find that the optimal mass ratio of WS 2 is 60%. As expected, the optimal electrode exhibits a high specific capacity (650 mAh/g at 0.1 A/g after 100 cycles) and ultra-long cycle stability (400 mAh/g at 1.0 A/g after 5000 cycles).