Butterfly architecture of NIR Aza-BODIPY small molecules decorated with phenothiazine or phenoxazine.

This is the first report on the highest efficiency NIR absorbing Aza-Bodipy small molecules. The molecular engineering of newly synthesized NIR absorbing Aza-Bodipy dyes consists of covalently linked phenothiazine (AZA-PTZ-BOD) and phenoxazine (AZA-POZ-BOD) moieties as terminal groups and Aza-Bodipy as a central core moiety. The highest efficiency for OPV devices of 8.23% is achieved for AZA-PTZ-BOD.