Unit-Emitting Carbon Dots.

Understanding the photoluminescence mechanisms of carbon dots (C-dots) is of importance for both fundamental science and their corresponding applications. In this study, we verify the emitting-unit model of C-dots by an upgraded "contrastive analysis" research paradigm. Employing preparative thin-layer chromatography, we recently developed polyamide column chromatography separation techniques, and four kinds of highly correlative C-dots are obtained from a homologous sample made from ortho -aminophenol precursors. Combining comprehensive experimental characterizations, especially the direct evidence from electrospray ionization mass spectrometry, we demonstrate that the photoluminescence of the four C-dots comes from the same polycyclic aromatic hydrocarbon units (named as emitting units) indeed, although these C-dots have substantially different chemical compositions.