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Anisotropy-driven quantum criticality in an intermediate valence system.

Mihael S GrbićEoin C T O'FarrellYosuke MatsumotoKentaro KugaManuel BrandoRobert KüchlerAndriy H NevidomskyyMakoto YoshidaToshiro SakakibaraYohei KonoYasuyuki ShimuraMichael L SutherlandMasashi TakigawaSatoru Nakatsuji
Published in: Nature communications (2022)
Intermetallic compounds containing f-electron elements have been prototypical materials for investigating strong electron correlations and quantum criticality (QC). Their heavy fermion ground state evoked by the magnetic f-electrons is susceptible to the onset of quantum phases, such as magnetism or superconductivity, due to the enhanced effective mass (m * ) and a corresponding decrease of the Fermi temperature. However, the presence of f-electron valence fluctuations to a non-magnetic state is regarded an anathema to QC, as it usually generates a paramagnetic Fermi-liquid state with quasiparticles of moderate m * . Such systems are typically isotropic, with a characteristic energy scale T 0 of the order of hundreds of kelvins that require large magnetic fields or pressures to promote a valence or magnetic instability. Here we show the discovery of a quantum critical behaviour and a Lifshitz transition under low magnetic field in an intermediate valence compound α-YbAlB 4 . The QC origin is attributed to the anisotropic hybridization between the conduction and localized f-electrons. These findings suggest a new route to bypass the large valence energy scale in developing the QC.
Keyphrases
  • molecular dynamics
  • molecularly imprinted
  • energy transfer
  • small molecule
  • ionic liquid
  • electron transfer
  • single molecule
  • simultaneous determination
  • liquid chromatography
  • tandem mass spectrometry