In Situ Immobilization of Palladium Nanodots in C-C Bonded 2D Conjugated Polymers through Suzuki Polymerization at the Liquid-Liquid Interface.

Traditional methods for immobilization of noble metal nanodots in 2D materials (2DMs) need multiple steps and unfriendly reaction conditions. Herein, a one-step method was developed by immobilizing in situ palladium nanodots during the preparation of the 2D conjugated polymer (2DCP) through Suzuki polymerization on interface under mild conditions. Through this method, three 2D conjugated nanosheets carrying palladium nanodots were synthesized.