The Influence of Residual Stresses on the Curve Shape-Describing Interface Behavior in "Polymer-Fiber" Systems.

The pull-out method was used to study the adhesive strength τ of "fiber-thermoset" systems with wide variations in area. Studied binders were based on resins that had different chemical natures (epoxy, epoxy phenol, orthophthalic, polyphenylsiloxane, and phenol-formaldehyde). Shear adhesive strength was determined for systems with two fiber types (glass and steel fibers). It was shown that strength τ depended on scale (area). Formation of τ occurred during the curing process and the system's subsequent cooling to the measurement temperature T. It was found that interface strength depended on measurement temperature across a wide temperature range that covered the highly elastic and the glassy state of the adhesive. The influence of residual stresses τ res , acting at the "binder-fiber" interface, on the nature of the curves describing the dependence of the adhesive strength on the studied factor was experimentally shown. A qualitative explanation of the observed regularities is proposed.