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Nitrogen-Doped Bismuth Nanosheet as an Efficient Electrocatalyst to CO 2 Reduction for Production of Formate.

Sanxiu LiYufei KangChenyang MoYage PengHaijun MaJuan Peng
Published in: International journal of molecular sciences (2022)
Electrochemical CO 2 reduction (CO 2 RR) to produce high value-added chemicals or fuels is a promising technology to address the greenhouse effect and energy challenges. Formate is a desirable product of CO 2 RR with great economic value. Here, nitrogen-doped bismuth nanosheets (N-BiNSs) were prepared by a facile one-step method. The N-BiNSs were used as efficient electrocatalysts for CO 2 RR with selective formate production. The N-BiNSs exhibited a high formate Faradic efficiency (FE formate) of 95.25% at -0.95 V (vs. RHE) with a stable current density of 33.63 mA cm -2 in 0.5 M KHCO 3 . Moreover, the N-BiNSs for CO 2 RR yielded a large current density (300 mA cm -2 ) for formate production in a flow-cell measurement, achieving the commercial requirement. The FE formate of 90% can maintain stability for 14 h of electrolysis. Nitrogen doping could induce charge transfer from the N atom to the Bi atom, thus modulating the electronic structure of N-Bi nanosheets. DFT results demonstrated the N-BiNSs reduced the adsorption energy of the *OCHO intermediate and promoted the mass transfer of charges, thereby improving the CO 2 RR with high FE formate . This study provides a valuable strategy to enhance the catalytic performance of bismuth-based catalysts for CO 2 RR by using a nitrogen-doping strategy.
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