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Novel Beta-Functionalized Porphyrins Approaching 11% Efficiency for Organic Solar Cells.

Yinchun GuoJifa WuZhenkun LinFeng TangLin YuanHanping WuXiaobin Peng
Published in: ACS applied materials & interfaces (2024)
Porphyrins and their derivatives possess high molar extinction coefficients and strong electron-donating abilities and have been widely used in organic solar cells (OSCs). Though porphyrins can be easily functionalized at the four meso-positions and the eight β-positions, nearly all porphyrin photovoltaic materials are reported to be functionalized at the meso-positions, and the porphyrin photovoltaic materials functionalized at the β-positions are to be explored. Herein, the regioselective β-positions of a porphyrin are first brominated without using rare metal iridium catalysts, and then, after two more reactions, two antipodal β-substituted porphyrin donors EHDPP-Por and BODPP-Por are synthesized, in which four DPP (diketopyrrolopyrrole) units are connected symmetrically with acetylene at four of the β-positions, for OSCs. The all-small-molecule organic solar cells based on EHDPP-Por:Y6 and BODPP-Por:Y6 active layers achieved power conversion efficiencies of 10.19 and 10.99%, respectively, which are higher than most of the binary OSCs based on the porphyrins functionalized at the meso-positions, demonstrating that β-functionalized porphyrins are very promising for OSCs.
Keyphrases
  • solar cells
  • quantum dots
  • photodynamic therapy
  • small molecule
  • molecularly imprinted
  • metal organic framework
  • energy transfer
  • molecular docking
  • electron transfer
  • ionic liquid