Perovskite-derived structure modulation in the iron sulfate family.

Yuanqi LanQi YanXinyuan ZhangWenjiao YaoChenchen WangChun-Sing Lee Philip Lightfoot Yongbing Tang

Published in: Chemical communications (Cambridge, England) (2022)

We report the first example of a perovskite sulfate [Na 3 (H 2 O)]Fe(SO 4 ) 3 . Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na 6 Fe(SO 4 ) 4 and Na 12 Fe 3 (SO 4 ) 6 F 8 . Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.

Keyphrases

room temperature
high efficiency
solar cells
metal organic framework
aqueous solution
ionic liquid
visible light
drug induced
perovskite solar cells