Transcription-induced formation of paired Al sites in high-silica CHA-type zeolite framework using Al-rich amorphous aluminosilicate.
Mizuho YabushitaYoshiyasu ImanishiTing XiaoRyota OsugaToshiki NishitobaSachiko MakiKiyoshi KanieWenbin CaoToshiyuki YokoiAtsushi MuramatsuPublished in: Chemical communications (Cambridge, England) (2021)
The paired Al species pre-formed in Al-rich amorphous aluminosilicates were transcribed into high-silica CHA-type zeolite frameworks under hydrothermal conditions, which offers a new approach to creating paired Al sites in zeolite frameworks. This Al-pair-rich CHA exhibited a higher Sr2+ uptake than the control CHA zeolite synthesized by the conventional procedure.