Self-Assemblies of Carboxylic Acid Derivatives with Different Symmetry: Adjusting by Solvent and Guest Molecules.

In this research, the self-assembly behaviors of two different symmetry carboxylic acid derivatives ( H 3 BTE and H 4 BTE ) regulated by solvent and guest molecule (coronene, COR) were explored at the liquid/solid interface by scanning tunneling microscopy, and the formation mechanism was investigated by density functional theory. In 1-phenyloctane, only H 3 BTE molecules dissolved with extremely low concentration and self-assembled into a honeycomb structure and a new strip structure, while H 4 BTE could not. In 1-heptanoic acid, H 3 BTE and H 4 BTE were easily dissolved, in which H 3 BTE formed a regular row structure and H 4 BTE formed a tetragonal structure, respectively. The host-guest interaction was investigated by introducing the COR molecules into their self-assembly structures, and due to the different symmetry, H 3 BTE and H 4 BTE displayed different accommodation behavior.