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Naphthalene Bis(4,8-diamino-1,5-dicarboxyl)amide Building Block for Semiconducting Polymers.

Brian J EcksteinFerdinand S MelkonyanEric F ManleySimone FabianoAidan R MouatLin X ChenAntonio FacchettiTobin J Marks
Published in: Journal of the American Chemical Society (2017)
We report a new naphthalene bis(4,8-diamino-1,5-dicarboxyl)amide (NBA) building block for polymeric semiconductors. Computational modeling suggests that regio-connectivity at the 2,6- or 3,7-NBA positions strongly modulates polymer backbone torsion and, therefore, intramolecular π-conjugation and aggregation. Optical, electrochemical, and X-ray diffraction characterization of 3,7- and 2,6-dithienyl-substituted NBA molecules and corresponding isomeric NBA-bithiophene copolymers P1 and P2, respectively, reveals the key role of regio-connectivity. Charge transport measurements demonstrate that while the twisted 3,7-NDA-based P1 is a poor semiconductor, the planar 2,6-functionalized NBA polymers (P2-P4) exhibit ambipolarity, with μe and μh of up to 0.39 and 0.32 cm2/(V·s), respectively.
Keyphrases
  • ionic liquid
  • high resolution
  • resting state
  • white matter
  • molecularly imprinted
  • molecular docking
  • magnetic resonance
  • high speed
  • electron microscopy
  • dual energy
  • simultaneous determination