Strontium Fluoride and Zinc Oxide Stacked Structure as an Interlayer in High-Performance Inverted Polymer Solar Cells.

Enhanced power conversion efficiency is reported in inverted polymer solar cells when an ultrathin layer of strontium fluoride (SrF2) is evaporated on the surface of the solution-processed zinc oxide (ZnO) electron transport layer. The photoactive layer is made up of bulk heterojunction composites of poly[4,8-bis(5(2-ethylhexyl)thiophen-2-yl)benzo[1,2- b:4,5- b']dithiopheneco-3-fluorothieno[3,4- b]-thiophene-2-carboxylate] and [6,6]-phenyl-C71-butyric acid methyl ester. The ZnO film acts as an effective electron transport layer, whereas the ultrathin SrF2 layer improves the energy level alignment and enhances the built-in potential via the formation of an interfacial dipole layer at the interfaces between the ZnO film and the photoactive layer, resulting in an enhanced electron extraction efficiency and a decreased carrier recombination loss. Furthermore, the SrF2 layer reduces the inherent incompatibility between the hydrophilic ZnO film and the hydrophobic photoactive layer. As a result, all the photovoltaic performance parameters are remarkably improved, leading to a high efficiency of up to 10.46% (with a fill factor of 71.38%), corresponding to a ca. 21% improvement over the reference device performance (8.64%). The use of a ZnO/SrF2 stacked interlayer provides a simple, but effective, approach to obtain high-efficiency inverted PSCs.