Synthesis, Optical Properties, and Applications of Luminescent Benzothiazole: Base Promoted Intramolecular C-S Bond Formation.

A novel base-catalyzed method for the synthesis of luminescent benzothiazole derivatives had been developed under metal-free conditions via C-S bond formation, which provided an efficient, convenient, and mild alternative method for constructing substituted benzothiazoles. As-prepared benzothiazole derivatives thus produced emissions in solution with quantum yield up to 85%. In addition, they still exhibited fairly strong fluorescence in the solid state. Furthermore, the compounds were used as a facile "On-Off" fluorescence probe to create handy test strips for detecting NaClO by naked eyes.