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Electrodeposition of Molybdenum Disulfide (MoS 2 ) Nanoparticles on Monocrystalline Silicon.

Martina VizzaWalter GiurlaniLorenzo CerriNicola CalisiAntonio Alessio LeonardiMaria Jose Lo FaroAlessia IrreraEnrico BerrettiJuan Victor Perales-RondonAlvaro ColinaElena Bujedo SaizMassimo Innocenti
Published in: Molecules (Basel, Switzerland) (2022)
Molybdenum disulfide (MoS 2 ) has attracted great attention for its unique chemical and physical properties. The applications of this transition metal dichalcogenide (TMDC) range from supercapacitors to dye-sensitized solar cells, Li-ion batteries and catalysis. This work opens new routes toward the use of electrodeposition as an easy, scalable and cost-effective technique to perform the coupling of Si with molybdenum disulfide. MoS 2 deposits were obtained on n -Si (100) electrodes by electrochemical deposition protocols working at room temperature and pressure, as opposed to the traditional vacuum-based techniques. The samples were characterized by X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM) and Rutherford Back Scattering (RBS).
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