Novel Approach to Synthesis of AgZnS and TiO 2 Decorated on Reduced Graphene Oxide Ternary Nanocomposite for Hydrogen Evolution Effect of Enhanced Synergetic Factors.
Jingjing ZhaoMd Nazmodduha RafatChang-Min YoonWon-Chun OhPublished in: Nanomaterials (Basel, Switzerland) (2022)
In this work, a novel ternary nanocomposites AgZnS-TiO 2 -reduced graphene oxide (RGO) was successfully synthesized by a facile soft ultrasonic-reduction condition as low as 70 °C. During the ultrasound reaction, the reduction of GO and the growth of AgZnS and TiO 2 crystals occurred simultaneously in conjunction with the deposition of AgZnS and TiO 2 crystals onto the surface of the graphene. The synthesized nanocatalysts were characterized by XRD, SEM, TEM, EDX, Raman spectroscopy, XPS, UV-Vis DRS, photoluminescence spectrometer, and photocurrent and CV. The AgZnS-G-T was shown as catalytic HER with some synnegetic factors such as pH-universal, temperature, and ultrasonic condition. After 4 h, it was observed that AgZnS-TiO 2 -RGO has the highest efficiency of photocatalytic activity through hydrogen production by water splitting, which achieved the highest hydrogen evolution rate of 930.45 μmol/g at buffer solution (pH = 5), which was superior to AgZnS-G (790.1 µmole/g) and AgZnS (701.2 µmole/g). Such a significant hydrogen evolution amount far exceeded that of undoped TiO 2 and RGO. The H 2 evolution amounts increased significantly at ultrasonic irradiation power of 80 MHz. AgZnS-G-T demonstrates the higher H 2 evolution amounts of 985 µmole/g at 80 MHz. Its photocatalytic hydrogen-evolution activity remained at a high level over four cycles (16 h) nanoparticle.