Catalytic Reactivity of Molybdenum-Trihalide Complexes Bearing PCP-Type Pincer Ligands.
Aya EizawaKazuya ArashibaAkihito EgiHiromasa TanakaKazunari NakajimaKazunari YoshizawaYoshiaki NishibayashiPublished in: Chemistry, an Asian journal (2019)
Molybdenum-iodide complexes bearing a PCP[1] ligand have been found to work as excellent catalysts toward ammonia formation under ambient reaction conditions among dinitrogen-bridged dimolybdenum complexes and other molybdenum complexes bearing PNP and PCP[2] ligands.