A redetermination of the structure and Hirshfeld surface analysis of poly[di-aquadi-μ-hydroxido-tetra-kis-(μ-nicotinato N-oxide)tricopper(II)].
Masoud MirzaeiMaryam BazarganPouria EbtehajJoel T MaguePublished in: Acta crystallographica. Section E, Crystallographic communications (2021)
The product obtained from the reaction of pyridine-2,3-di-carb-oxy-lic acid and hydrated copper(II) chloride in hot aqueous NaOH solution was determined by low temperature X-ray diffraction to be [Cu3(C6H4NO3)4(OH)2(H2O)2] n or [Cu3(μ-OH)2(μ-nicNO)4(H2O)2] n (nicNO is pyridine-3-carboxyl-ate N-oxide), a structure obtained from room temperature data and reported previously. The present determination is improved in quality and treatment of the H atoms. A Hirshfeld surface analysis of the inter-molecular inter-actions is presented.
Keyphrases
- crystal structure
- room temperature
- ionic liquid
- biofilm formation
- high resolution
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- aqueous solution
- oxide nanoparticles
- metal organic framework
- electron microscopy
- escherichia coli
- solid phase extraction
- big data
- magnetic resonance imaging
- machine learning
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- pseudomonas aeruginosa
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- candida albicans
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- electron transfer
- solid state