Electronic Oxide-Metal Strong Interaction (EOMSI).

Strong metal-support interaction of supported metal catalysts is an important concept to describe the effect of metal-support interactions on the structures and catalytic performances of supported metal particles. By using an example of CeOx adlayers supported on Ag nanocrystals, herein a concept of electronic oxide-metal strong interaction (EOMSI) is put forward; this interaction significantly affects the electronic structures of oxide adlayers through metal-to-oxide charge transfer. The EOMSI can stabilize oxide adlayers in a low oxidation state under ambient conditions, which individually are not stable; moreover, the oxide adlayers experiencing the EOMSI are resistant to high-temperature oxidation in air to a certain extent. Such an EOMSI concept helps to generalize the strong influence of oxide-metal interactions on the structures and catalytic performance of oxide/metal inverse catalysts, which have been attracting increasing attention.