Enhanced Degradation of Rhodamine B by Metallic Organic Frameworks Based on NH 2 -MIL-125(Ti) under Visible Light.

Samples of the bimetallic-based NH 2 -MIL-125(Ti) at a ratio of M n+ /Ti 4+ is 0.15 (M n+ : Ni 2+ , Co 2+ and Fe 3+ ) were first synthesized using the solvothermal method. Their fundamental properties were analyzed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectra, scanning electron microscopy (SEM), N 2 adsorption-desorption measurements, and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). The as-acquired materials were used as high-efficiency heterogeneous photocatalysts to remove Rhodamine B (RhB) dye under visible light. The results verified that 82.4% of the RhB (3 × 10 -5 M) was degraded within 120 min by 15% Fe/Ti-MOFs. Furthermore, in the purpose of degrading Rhodamine B (RhB), the rate constant for the 15% Fe/Ti-MOFs was found to be 2.6 times as fast as that of NH 2 -MIL-125(Ti). Moreover, the 15% Fe/Ti-MOFs photocatalysts remained stable after three consecutive cycles. The trapping test demonstrated that the major active species in the degradation of the RhB process were hydroxyl radicals (HO ∙ ) and holes (h + ).