MOF-Derived Fe-Doped Ni@NC Hierarchical Hollow Microspheres as an Efficient Electrocatalyst for Alkaline Oxygen Evolution Reaction.

The development of low-cost and efficient electrocatalysts for oxygen evolution reaction (OER) is of great importance for producing hydrogen via water splitting. Metal-organic frameworks (MOFs) provide an opportunity for the facile preparation of high-efficiency OER electrocatalysts. In this work, we prepared iron-doped nickel nanoparticles encapsulated in nitrogen-doped carbon microspheres (Fe-Ni@NC) with a unique hierarchical porous structure by directly pyrolyzing the MOF precursor for effectively boosting OER. The Fe doping has a significant enhancement effect on the catalytic performance. The optimized Fe (5%)-Ni@NC catalyst represents a remarkable activity with an overpotential of 257 mV at 10 mA cm-2 and superior stability toward OER in 1.0 M KOH.