A Co-Doping Materials Design Strategy for Selective Ozone Electrocatalysts.

Catalysts for electrochemical ozone production (EOP) face inherent selectivity challenges stemming from thermodynamic constraints. This work establishes a design strategy for minimizing these limitations and inducing EOP activity in tin oxide, which is an intrinsically EOP-inactive material. We propose that selective ozone production using tin oxide catalysts can be broadly achieved by co-doping with two elements: first, n-type dopants to enhance electrical conductivity, and second, transition metal dopants that leach and homogeneously generate essential hydroperoxyl radical intermediates. Synthesizing tantalum, antimony, and tungsten n-type dopants with nickel, cobalt, and iron as transition metal dopants confirms that properly co-doping tin oxide yields EOP-active catalysts. This study offers a robust framework for advancing EOP catalyst design and serves as a case study for the application of fundamental co-catalysis and solid-state physics principles to induce catalytic activity in inert materials.