Lattice Strain Mediated Reversible Reconstruction in CoMoO 4 ·0.69H 2 O for Intermittent Oxygen Evolution.

A heterogeneous interface usually plays a versatile role in modulating catalysis and the durability of hybrid electrocatalysts for oxygen evolution reaction (OER), and its intrinsic mechanism is still in dispute due to an uncertain correlation of initial, intermediate and active phases. In this article, the CoMoO 4 ·0.69H 2 O/Co 3 O 4 heterogeneous interface is configured to understand the evolution kinetics of these correlated phases. Due to the chemically and electrochemically "inert" character of Co 3 O 4 support, lattice strain with 3.31% tuning magnitude in primary CoMoO 4 ·0.69H 2 O can be inherited after spontaneous dissolution of molybdenum cations in electrolyte, dominating catalytic activity of the reconstructed CoOOH. In situ Raman spectroscopy demonstrates reversible conversion between active CoOOH and amorphous cobalt oxide during OER when positive and negative potentials are sequentially supplied onto hybrid catalysts with favorable strain. Therefore, superior durability with negligible decay after 10 cycles is experimentally identified for intermittent oxygen evolution. Theoretical calculations indicate that appropriate stress within the electrocatalyst could reduce the reaction energy barrier and enhance the OER performance by optimizing the adsorption of intermediates.