Polyaniline-Encapsulated Metal-Organic Framework MIL-101: Adsorbent with Record-High Adsorption Capacity for the Removal of Both Basic Quinoline and Neutral Indole from Liquid Fuel.

Polyaniline-encapsulated metal-organic frameworks (MOFs; MIL-101, Cr-benzenedicarboxylate) were prepared via a ship-in-bottle strategy and applied in liquid phase adsorptions. The modified MIL-101s showed record-high adsorptions for both basic and neutral nitrogen-containing compounds (NCCs) from liquid model fuel. For example, the maximum adsorption capacities ( Qo) of the protonated polyaniline (pANI)@MIL-101 for the basic quinoline and neutral indole from n-octane were 556 and 602 mg/g, respectively. The plausible adsorption mechanisms such as hydrogen bonding, acid-base interaction, and cation-π interaction were proposed to explain the extraordinary adsorptions of the studied adsorbates. Moreover, the adsorbents could be recycled via a simple approach and reused in adsorptions without noticeable decrease in performances. Therefore, the pANI-encapsulated MOFs could be recommended as a new type of adsorbents for very efficient removal of both basic and neutral NCCs from liquid fuel.