Synthesis of Metallomacrocycle and Coordination Polymers with Pyridine-Based Amidocarboxylate Ligands and Their Catalytic Activities towards the Henry and Knoevenagel Reactions.

The reactions of 3,3'-{(pyridine-2,6-dicarbonyl)bis(azanediyl)}dibenzoic acid (H2L) with zinc(II), cadmium(II), and samarium(III) nitrates were studied, and the obtained compounds, [Zn(1κO:2κO'-L)(H2O)2] n (1), [Cd(1κO 2:2κO 2-L)(H2O)2]2 ⋅6n H2O⋅ n C4H8O2 ⋅1.5n DMF (2), and [Sm(1κO:2κO'O'':3κO'''-L)(NO3)(H2O)(dmf)] n ⋅ n DMF (3), were characterized by elemental analysis, FTIR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. Compounds 1 and 3 have 1D zigzag- and double-chain-type structures, respectively, whereas 2 features a dinuclear metallomacrocyclic complex. The ligand (L2-) orients in different conformations, that is, syn-syn for 1 and anti-anti for 2 and 3. Compound 1 is the first example in which the syn-syn conformation for this ligand has been observed. These compounds act as heterogeneous catalysts for the nitroaldol (Henry; in water medium) and Knoevenagel condensation reactions of different aldehydes, and the most effective is zinc coordination polymer 1. Recyclability, heterogeneity, and size-selectivity tests were performed, which showed that the catalyst was highly active over at least four recycling runs.