Edge Rich Ultrathin Layered MoS 2 Nanostructures for Superior Visible Light Photocatalytic Activity.

Nanostructures of layered 2D materials have been proven one of the significant recent trends for visible-light-driven photocatalysis because of their unique morphology, effective optical adsorption, and rich active sites. Herein, we synthesized ultrathin-layered MoS 2 nanoflowers and nanosheets with rich active sites by using a facile hydrothermal technique. The photocatalytic performance of the as-synthesized MoS 2 nanoflowers (NF) and nanosheets (NS) were investigated for the photodegradation of MB (methylene blue), MG (malachite Green), and RhB (rhodamine B) dye under visible light irradiations. Ultrathin-layered nanoflowers showed faster degradation (96% in 150 min) in RhB under visible light irradiation, probably due to a large number of active sites and high available surface area. The kinetic study demonstrated that the first-order kinetic model best explained the process of photodegradation. The MoS 2 nanoflowers catalysts has similar catalytic performance after four consecutive cyclic performances, demonstrating their good stability. The results showed that the MoS 2 nanoflowers have outstanding visible-light-driven photocatalytic activity and could be an effective catalyst for industrial wastewater treatment.