Login / Signup

Lead-Free BiFeO3-BaTiO3 Ceramics with High Curie Temperature: Fine Compositional Tuning across the Phase Boundary for High Piezoelectric Charge and Strain Coefficients.

Bowei XunAizhen SongJingru YuYang YinJing-Feng LiBo-Ping Zhang
Published in: ACS applied materials & interfaces (2021)
BiFeO3-BaTiO3 is a promising high-temperature piezoelectric ceramic that possesses both good electromechanical properties and a Curie temperature (TC). Here, the piezoelectric charge constants (d33) and strain coefficients (d*33) of (1 - x)BiFeO3-xBaTiO3 (BF-xBT; 0.20 ≤ x ≤ 0.50) lead-free piezoelectrics were investigated at room temperature. The results showed a maximum d33 of 225 pC/N in the BF-0.30BT ceramic and a maximum d*33 of 405 pm/V in the BF-0.35BT ceramic, with TCs of 503 and 415 °C, respectively. To better understand the performance enhancement mechanisms, a phase diagram was established using the results of XRD, piezoresponse force microscopy, TEM, and electrical property measurements. The superb d33 of the BF-0.30BT ceramic arose because of its location in the optimum point in the morphotropic phase boundary, low oxygen vacancy (VO··) concentration, and domain heterogeneity. The superior d*33 of the BF-0.35BT ceramic was attributed to a weak relaxor behavior between coexisting macrodomains and polar nanoregions. The presented strategy provides guidelines for designing high-temperature BF-BT ceramics for different applications.
Keyphrases
  • high temperature
  • room temperature
  • air pollution
  • single molecule
  • ionic liquid
  • particulate matter
  • single cell
  • clinical practice
  • mass spectrometry
  • high speed
  • polycyclic aromatic hydrocarbons
  • atomic force microscopy