Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.

Huatian ShiJianhui XieWilliam W Y LamWai-Lun ManChi-Keung MakShek-Man YiuHung Kay LeeTai-Chu Lau

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2019)

The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV (TAML)(N-Mes)]- (1), are reported. Compound 1 is oxidized by [(p-BrC6 H4 )3 N]+. [SbCl6 ]- and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.

Keyphrases

electron transfer
low density lipoprotein
high resolution
molecular dynamics
electron microscopy
magnetic resonance imaging
mass spectrometry
dual energy
genetic diversity