An Alumino-Mannich Reaction of Organoaluminum Reagents, Silylated Amines, and Aldehydes.
Anika TarasewiczDeeba EnsanRobert T BateyPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2018)
A multi-component coupling using organoaluminum reagents, silylated amines, and aldehydes results in the formation of tertiary amines. Both alkenyl- and alkylaluminum reagents undergo reaction with iminium ion substrates for which the corresponding Petasis borono-Mannich reactions are unsuccessful.
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