Phosphorescent Carbon Dots as Long-Lived Donors To Develop an Energy Transfer-Based Sensing Platform.
Taotao LiXinyi LiYu ZhengPan ZhuCheng ZhangKui ZhangJing-Juan XuPublished in: Analytical chemistry (2023)
Employing long-lived luminescent materials to design a chemical sensing platform can eliminate real-time excitation and background fluorescence. However, the realization of long-lived emissions in aqueous media was limited to transition-metal complexes, doped quantum dots, organic crystals, and inorganic persistent phosphors, which suffer from the drawbacks of large size, expensive elements, and poor dispersibility. In this work, phosphorescent carbon dots (CDs) were covalently immobilized in a silica matrix (CDs@SiO 2 ) to achieve afterglow emission in an aqueous dispersion. CDs@SiO 2 with long lifetime (∼1.6 s) was utilized as an energy donor to fabricate nonradiative energy transfer systems with various organic dyes through the surface micelle self-assembly method. Benefiting from the high energy transfer efficiency between CDs@SiO 2 and organic dyes, multicolor afterglow emissions were successfully obtained in aqueous media. As a proof of concept, a ratiometric phosphorescent probe using CDs@SiO 2 as a donor and Hg 2+ -responsive rhodamine derivative as an acceptor was designed. Hg 2+ triggered the energy transfer process between the donor-acceptor pair, leading to the sensitive detection of Hg 2+ ions. The work presented here provides opportunities to develop chemical sensors with low background interferences and easily recognizable signals.
Keyphrases
- quantum dots
- energy transfer
- sensitive detection
- fluorescent probe
- aqueous solution
- water soluble
- ionic liquid
- magnetic nanoparticles
- living cells
- transition metal
- high throughput
- risk assessment
- light emitting
- cancer therapy
- room temperature
- metal organic framework
- low cost
- hydrogen peroxide
- life cycle
- municipal solid waste
- capillary electrophoresis