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Hierarchical Hybrid Nanostructures Constructed by Fullerene and Molecular Tweezer.

Minwook ParkKyeong-Im HongMinji KangTae-Wook KimHosoowi LeeWoo-Dong JangKwang-Un Jeong
Published in: ACS nano (2019)
For the construction of well-defined hierarchical superstructures of pristine [60]fullerene (C60) arrays, pyrene-based molecular tweezers (PT) were used as host molecules for catching and arranging C60 guest molecules. The formation of host-guest complexes was systematically studied in solution as well as in the solid state. Two-dimensional proton nuclear magnetic resonance spectroscopic studies revealed that PT-host and C60-guest complexes were closely related to the molecular self-assembly of PT. Ultraviolet and fluorescence spectroscopic titrations indicated the formation of stable 1:1 and 2:1 (PT/C60) complexes. From the nonlinear curve-fitting analysis, equilibrium constants for the 1:1 (log K1) and 2:1 (log K2) complexes were estimated to be 4.96 and 5.01, respectively. X-ray diffraction results combined with transmission electron microscopy observations clearly exhibited the construction of well-defined layered superstructures of the PT-host and C60-guest complexes. From electron mobility measurements, it was demonstrated that the well-defined hierarchical hybrid nanostructure incorporating a C60 array exhibited a high electron mobility of 1.7 × 10-2 cm2 V-1 s-1. This study can provide a guideline for the hierarchical hybrid nanostructures of host-guest complex and its applications.
Keyphrases
  • electron microscopy
  • solid state
  • magnetic resonance
  • molecular docking
  • single molecule
  • solar cells
  • water soluble
  • high resolution
  • magnetic resonance imaging
  • high throughput
  • molecular dynamics simulations