Vapour-phase deposition of oriented copper dicarboxylate metal-organic framework thin films.
Timothée StassinSabina Rodríguez-HermidaBenedikt SchrodeAlexander John CruzFrancesco CarraroDmitry KravchenkoVincent CreemersMark D AllendorfTom HauffmanDirk E De VosPaolo FalcaroRoland ReselRob AmelootPublished in: Chemical communications (Cambridge, England) (2019)
Copper dicarboxylate metal-organic framework films are deposited via chemical vapour deposition. Uniform films of CuBDC and CuCDC with an out-of-plane orientation and accessible porosity are obtained from the reaction of Cu and CuO with vaporised dicarboxylic acid linkers.