Liquid/Liquid Interfacial Suzuki Polymerization Prepared Novel Triphenylamine-Based Conjugated Polymer Films with Excellent Electrochromic Properties.

Preparing conjugated polymer films via interfacial Suzuki polymerization is a promising method for obtaining desirable electrochromic materials with desired structures. Here, a series of aryl boronic esters and triphenylamine-based aryl bromides were applied as precursors, and several polymer films were finally obtained via the liquid/liquid interfacial Suzuki polymerization reaction under mild conditions. FT-IR, UV, and Raman as well as electrochemistry, SEM, and EDS results all provide strong evidence for the formation of the desired polymer structures. Among them, the TPA-Wu (containing triphenylamine and alkyl-fluorene) film exhibits the best film-forming quality. Besides, these polymer films were applied in electrochromic applications. The results show that electrochromic properties can be affected by the quality of film formation. It is worth mentioning that the TPA-Wu film could achieve excellent electrochromic properties with reversible multicolor changes from transparent yellow to orange-red to blue-green under varying potentials. Compared to other triphenylamine-based electrochromic materials, the TPA-Wu film possessed the most desirable coloring efficiency, higher optical contrast, and shorter switching time. This work provides an existing general approach of liquid/liquid interfacial Suzuki polymerization for constructing conjugated polymer films toward electrochromic applications.