Precision syntheses of molecular necklaces based on coordination interactions.

Molecular necklaces (MNs) are mechanically interlocked molecules that have attracted considerable attention due to their delicate structures and potential applications, such as in the syntheses of polymeric materials and DNA cleavage. However, complex and lengthy synthetic routes have limited development of further applications. Owing to their dynamic reversibility, strong bond energy and high orientation, coordination interactions were employed to synthesize MNs. In this review, progress in the coordination-based MNs has been summarized, with emphasis on design strategies and potential applications based on coordination interactions.