Carbon Nitride Decorated Ball-Flower like Co₃O₄ Hybrid Composite: Hydrothermal Synthesis and Ethanol Gas Sensing Application.

Recently, semiconducting metal oxide (SMO) gas sensors have attracted the attention of researchers for high conductivity, labile features by environment, low cost, easy preparation, etc. However, traditional SMOs have some defects such as higher operating temperature and lower response value, which greatly limit their application in the field of gas sensor. In this work, the carbon nitride decorated ball-flower like Co₃O₄ composite was successfully synthesized via a facile hydrothermal method, the composition and morphology of the as-synthesized samples were studied by the techniques of X-ray powder diffraction (XRD), Field-emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), Fourier transform infrared spectrometer (FT-IR) and N₂-sorption. As a consequence, the pure Co₃O₄ and the carbon nitride decorated Co₃O₄ both possess ball-flower like structure, and the as-synthesized carbon nitride decorated Co₃O₄ composite exhibits significant sensing properties to ethanol which is 1.6 times higher than that of pure Co₃O₄, furthermore, the composite possesses high selectivity and stability towards ethanol detection.