A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins.

Published in: Organic letters (2020)

An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described. A wide variety of trans-2-olefins bearing various functional groups can be obtained with high regio- and stereoselectivity under mild reaction conditions. The ligand is crucial for the reaction.

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