Hydrolytic vs. Nonhydrolytic Sol-Gel in Preparation of Mixed Oxide Silica-Alumina Catalysts for Esterification.

The development of green and sustainable materials for use as heterogeneous catalysts is a growing area of research in chemistry. In this paper, mesoporous SiO 2 -Al 2 O 3 mixed oxide catalysts with different Si/Al ratios were prepared via hydrolytic (HSG) and nonhydrolytic sol-gel (NHSG) processes. The HSG route was explored in acidic and basic media, while NHSG was investigated in the presence of diisopropylether as an oxygen donor. The obtained materials were characterized using EDX, N 2 -physisorption, powder XRD, 29 Si, 27 Al MAS-NMR, and NH 3 -TPD. This approach offered good control of composition and the Si/Al ratio was found to influence both the texture and the acidity of the mesoporous materials. According to 27 Al and 29 Si MAS NMR analyses, silicon and aluminum were more regularly distributed in NHSG samples that were also more acidic. Silica-alumina catalysts prepared via NHSG were more active in esterification of acetic acid with n-BuOH.