Beyond Crystal Engineering: Significant Enhancement of C2H2/CO2 Separation by Constructing Composite Material.

Hui Qiong WuChang Sheng YanFeng Luo Rajamani Krishna

Published in: Inorganic chemistry (2018)

Different from the established crystal engineering method for enhancing gas-separation performance, we demonstrate herein a distinct approach. In contrast to the pristine MOF (metal-organic framework) material, the C2H2/CO2 separation ability for the resultant Ag NPs (nanoparticle)@Fe2O3@MOF composite material, estimated from breakthrough calculations, is greatly enhanced by 2 times, and further magnified up to 3 times under visible light irradiation.

Keyphrases

metal organic framework
visible light
liquid chromatography
magnetic resonance
mass spectrometry
molecular dynamics
quantum dots
molecular dynamics simulations
density functional theory
computed tomography
radiation therapy
radiation induced
contrast enhanced