Azobenzene-Based Ionic Liquid Switches Phase Separation of Poly( N -isopropylacrylamide) Aqueous Solutions as a Molecular Trigger, Leading to UV Shutdown of Ionic Transport.

This paper presents a light-switchable phase separation of poly( N -isopropylacrylamide) (PNIPAm) in aqueous solutions using an azobenzene-based ionic liquid as a molecular trigger. A different UV response was obtained with use of an azobenzene molecular trigger. A UV-induced aggregation of PNIPAm was observed in the current system, which is opposite to that reported for azobenzene-functionalized PNIPAm systems. According to in situ FT-IR, cis -isomers destabilized the hydrogen bonding between water and PNIPAm, contributing to a light-induced aggregation of PNIPAm. This polarity effect was quite similar to salting effects of hofmeister anions on clouding points. Furthermore, a UV shutdown of ion transport of the azobenzene-based ionic liquid was demonstrated with a significant reduction factor of 0.03 at ambient temperature, which can be potentially applied in biotechnology, optoelectronics, and ionic circuits.