Deep Eutectic Liquids as Tailorable Extraction Solvents: A Review of Opportunities and Challenges.

Deep Eutectic Liquids (DELs) fall among the rapidly evolving discoveries of the 21 st century, and these liquids are considered as alternative solvents to toxic and volatile organic liquids. Nevertheless, the emerging trend regarding the use of DELs in every field of physical and biological sciences, a lot of ambiguities and misconceptions exist about their formation, mechanism, and efficiencies observed or projected. A review of available technical data makes it obvious that these liquids have the potential to revolutionize the underdeveloped areas of analytical chemistry particularly the extraction/enrichment of analytes. To ensure the green and sustainable use of DELs, the researchers need to have a thorough understanding of DELs, their classification, chemistry, the nature and strength of molecular entanglements, and their tailorable features. Many researchers have declared these liquids recyclable but more attentive trials are needed to develop an authentic and straightforward DELs recycling methodology. The present review covers sound background knowledge and expert opinions about the technical definition of DELs, their classification, formation, recyclability, and tailorable features for their application as extraction solvent/sorbent in analytical chemistry.