Chiroptical induction with prism[5]arene alkoxy-homologs.
Xiaotong LiangYanling ShenDayang ZhouJiecheng JiHongtao WangTing ZhaoTadashi MoriWuanhua WuCheng YangPublished in: Chemical communications (Cambridge, England) (2022)
The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 10 7 M -1 , significant CD with g abs of up to 0.8 × 10 -2 and CPL with g lum of 2 × 10 -3 . The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes.